It's going to help shift the soil to the alkaline side. You can put fine ash in teaspoon amounts as a top dressing and then water. If your adding it to a soil mix prior to planting you want to make a solution of fine ash and water, test the pH of the solution and then water the soil to the point just before she's going to drip. If you want to shift your soil 1 pH unit then add a solution that is 1pH unit more alkaline than your desired end point. For example, you've got a 6 pH soil and you want it at 7 pH water the soil with an 8 pH solution of wood ash. Keep in mind you're going to need to be able to test your soil pH to ensure your on the spot. Make sure the soil mix has equilibrated for several weeks prior to planting.