First of all, add water 'till you get some "run-off". Then collect the run-off in a clean container and do a pH test on it. This will give an indication of how much Dolomite (if any), you might need to add. From here on it's just a balancing act between adding Dolomite and acheiveing the desired pH reading.
I suppose you could add the Dolomite to your water, but the conventional way it's done is to "Topdress" it in. Topdressing has a long, proven, track record of being effective. "Watering It In" sounds like it might work, it's just the easy way.