I had this EXACT problem a few weeks ago. I was running Iguana juice and Nirvana with some humics and fulvics too. My Ph was at 5.6 -5.7 for about 3 days. then I thought it would be good to add some beneficials to the mix (aquashield) but as soon as I added the stuff my ph jamped to over 7.0 there was no amount of ph down that would make it go lower than 6.5 then it would spring right back up again. I found out that my bottle of Aquashield was the culprit. Idk if it was bad or just crappy but it hasnt done it again. I would use everything else you are using but the aquashield. if you are worried about pythium do wut BR said and add some H202 but not if your using Botanicare nutes (they dont recommend it). If you want to continue using Botanicare I would pick up an enzyme product like sensizym from advanced. it is supposed to prevent /get rid of pythium, and its the only product ive used for this purpose and ive never had root rot, just big healthy roots.
-AN