http://www.oardc.ohio-state.edu/fruitpathology/organic/grape/organic.html You study you posted is good on of the 1st links I found when I was doing my home work but fails to say what kind of copper spay they are using .
Bordeaux Mixture
Bordeaux mixture is a mixture of copper sulfate and hydrated lime in water. It has long residual action and has been used for years to control many diseases, including downy mildew and powdery mildew of grape. It can be made (mixed) on site by combining copper sulfate with spray grade lime. It is also commercially available as a dry wettable powder.
Fixed Copper Fungicides
Following the discovery and use of Bordeaux mixture, several relatively insoluble copper compounds or fixed coppers were developed. Fixed copper formulations release less copper ions and are generally less injurious to plant tissues (safer to use) than Bordeaux mixture, but their use is still limited because of their potential to injure plants and lack of compatibility with other pesticides. Some of the more common commercial formulations of fixed copper include C-O-C-S, Kocide 101, Tribasic Copper sulfate, Champ, and Tenn-Copp 5E. There are several fixed copper fungicides registered for use on small fruit.
for controlling grape diseases.
[TABLE="width: 100%"]
[TR]
[TD][/TD]
[TD][/TD]
[TD="colspan: 5"]
Disease
[/TD]
[/TR]
[TR]
[TD="align: center"]
Material[/TD]
[TD="bgcolor: #FFFFCC, align: left"]
Anthracnose[/TD]
[TD="align: left"]
Black rot[/TD]
[TD="bgcolor: #FFFFCC, align: left"]
Powdery mildew [/TD]
[TD="align: left"]
Downy mildew [/TD]
[TD="bgcolor: #FFFFCC, align: left"]
Phomopsis cane and leaf spot[/TD]
[TD="align: left"]
Botrytis bunch rot [/TD]
[/TR]
[TR]
[TD]Lime sulfur[/TD]
[TD="bgcolor: #FFFFCC, align: center"]H[/TD]
[TD="align: center"]W[/TD]
[TD="bgcolor: #FFFFCC, align: center"]H[/TD]
[TD="align: center"]W[/TD]
[TD="bgcolor: #FFFFCC, align: center"]M[/TD]
[TD="align: center"]W[/TD]
[/TR]
[TR]
[TD]Sulfur[/TD]
[TD="bgcolor: #FFFFCC, align: center"]W[/TD]
[TD="align: center"]W[/TD]
[TD="bgcolor: #FFFFCC, align: center"]H[/TD]
[TD="align: center"]W[/TD]
[TD="bgcolor: #FFFFCC, align: center"]W[/TD]
[TD="align: center"]W[/TD]
[/TR]
[TR]
[TD]Copper fungicide[/TD]
[TD="bgcolor: #FFFFCC, align: center"]
M[/TD]
[TD="align: center"]
M[/TD]
[TD="bgcolor: #FFFFCC, align: center"]
H[/TD]
[TD="align: center"]
H[/TD]
[TD="bgcolor: #FFFFCC, align: center"]
W[/TD]
[TD="align: center"]
W[/TD]
[/TR]
[TR]
[TD]Horticulture grade spray oils[/TD]
[TD="bgcolor: #FFFFCC, align: center"]
W[/TD]
[TD="align: center"]
W[/TD]
[TD="bgcolor: #FFFFCC, align: center"]
H[/TD]
[TD="align: center"]
W[/TD]
[TD="bgcolor: #FFFFCC, align: center"]
W[/TD]
[TD="align: center"]
W[/TD]
[/TR]
[TR]
[TD]Salts: Monopotassium
Phosphate
Potassium bicarbonate
(Kaligreen, Armicarb)
[/TD]
[TD="bgcolor: #FFFFCC, align: center"]
W[/TD]
[TD="align: center"]
W[/TD]
[TD="bgcolor: #FFFFCC, align: center"]
H[/TD]
[TD="align: center"]
W[/TD]
[TD="bgcolor: #FFFFCC, align: center"]
W[/TD]
[TD="align: center"]
W[/TD]
[/TR]
[TR]
[TD]Hydrogen peroxide (oxidate)[/TD]
[TD="bgcolor: #FFFFCC, align: center"]
W[/TD]
[TD="align: center"]
W[/TD]
[TD="bgcolor: #FFFFCC, align: center"]
M[/TD]
[TD="align: center"]
W[/TD]
[TD="bgcolor: #FFFFCC, align: center"]
W[/TD]
[TD="align: center"]
W[/TD]
[/TR]
[/TABLE]
H= highly effective
M= moderately effective
W= weak or not effective