i'm guessing it's only on the top?
in a non-inert medium it isn't that uncommon for algae/moss type growths to form on the top of the soil, it's a reaction from the food (soil) and light, it's not a huge problem, i've never seen any issueswith it, just let it dry out a bit and it'll die. A fan directed to the medium will help also.
the perlite is white so you can see it easier, it forms on all the soil, you just can't see it as easy on darker surfaces.
I'm not familiar with the term "sour" pertaining to the soil, i'm assuming you are talking ph?
If you are, i don't agree algae/moss growth won't affect ph over the course of an indoor grow, maybe over years, not months.