Shake it and look inside with a flashlight or something. If you hear any gravel or see any rocks or stuff in the nutrients then it's not 100% good anymore. What can happen is call precipitation and that's when minerals start to bond together and become unusable to the plant. The chemistry joke for this is "If you're not part of the solution, then you're part of the precipitate." LOL I love that one.
Otherwise the shelf life for that is basically many years..