Coconut and aloe recommend time it’s good once in sprayer

Not sure if this is the right place to post this… just wondering how long is the powdered aloe and coconut safe to stay in a gallon sprayer. It smells a little rank and I’m not sure if that’s a ok or not. Also, any thoughts on why it would be lowering my waters PH? Idk if the ph pen is correctly calibrated but my well water from the tap is over 8. And now with the aloe powder and coconut powder it’s like 4.2??
 
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