There's really no 'right time' to add PK13/14. In any case, both your questions depend on what nutrients (NPK Ca mg ratio) you are using at the moment. You could use it a little to change the NPK ratio but using it as subscribed even at lower doses than recommended messes up the NPK ratio into one not actually desirable for cannabis plants.
I've grown LH from BF, took about 11-12 weeks, huge amount of foxtailing.