Nutrients are the best way to alter PH i compost, if you want it to stay that way.
Read up on how nutrients effect on media over time.
Here is something to wet your appetite:
"Put another way, applying 100 ppm of ammoniacal nitrogen has the potential to supply the same amount of acidity as a solution with a pH of 1.8. The acidity produced by a solution with a pH of 5.0 would be equivalent to the nitrification of 0.14 ppm ammoniacal nitrogen (almost undetectable). Also, doubling the concentration of ammonium from 100 to 200 ppm N doubles the acidity.
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In other words, no wonder simple acids doesn't do much over time.
It's all about the living soil, which changes it's PH according to nutrient-ratios and how the plants are using them.